Since you are talking about data DVDs (using UDF), ISO compatibility limits
you to 2GB but you can make a "pure" UDF disk and then you get past the 2GB
limit (not sure what the exact maximum is but presumably very large) . If
you have Nero, play with that and look at all the different ways you can
create a DVD

It's not very intuitive but in StartSmart select the Data
icon, then scroll to the right (ISO is the default on the left).